Anion-exchange behavior of Db in HF/HNO solution

Kato, Mizuho*; Adachi, Sadia*; Toyoshima, Atsushi*; Tsukada, Kazuaki; Asai, Masato; Haba, Hiromitsu*; Yokokita, Takuya*; Komori, Yukiko*; Shigekawa, Yudai*; Sueki, Keisuke*

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A few studies have been so far performed on aqueous chemistry of Db, the group-5 superheavy element, by anion-exchange experiments in HF and HF/HNO mixture solutions. Although the distribution coefficient (Kd) of Db was shown to trend to Ta Nb Db Pa in the group-5 homologs and pseudo-homolog elements, its chemical species has not been clarified. In this work, for identification of fluoride species of Db, we performed anion-exchange experiments of Nb, Ta, and Db in HF/1.0 M HNO mixture solutions by using an automated rapid chemistry apparatus, ARCA.